Online Sodium Analyser
Use the dedicated 3S-NA sodium analyser for online potentiometric ISE measurement.

Online Sodium Analyser with 3S
Sodium is measured by the separate 3S-NA analyser, not by the 3S-CL colorimetric platform. The 3S-NA uses potentiometric ion-selective electrode measurement and conditions the sample to reduce pH and ammonium interference before the sodium result is determined.
Applications include high-purity and process water, reverse-osmosis and demineralisation systems, condensate, boiler-feed water and steam-cycle monitoring. PMA reviews the expected sodium concentration, sample temperature, pressure and installation point before specification. Review the 3S analyser platform, explore water-analysis applications or discuss the sodium sample with PMA Support.
Continuous online sodium measurement with the 3S-NA
The conditioned sample flows to a glass sodium electrode, allowing operators to review continuous sodium results and analyser status through the integrated touchscreen.
01 / SODIUM ISE
Potentiometric sodium measurement
The glass sodium electrode develops a potential related to sodium concentration after reagent vapour raises the sample to pH 11 to reduce pH and ammonium interference.
- 0.1 ppb to 10 ppm measuring range
- T90 response of 180 seconds from 0 to 10 ppb
- Sample pH range from 4 to 11
02 / CALIBRATION
Automatic calibration and grab samples
The 3S-NA can provide one- or two-point calibration, with the NA-2 configuration adding automatic calibration and unattended grab-sample analysis.
- One- or two-point calibration
- Freely selectable calibration intervals
- Grab-sample results stored with date and time
Sodium analyser information
Current 3S-NA information for sodium measurement and installation review. The final configuration should be confirmed against the latest sodium datasheet.
Vertical installation
Wall or rack mounting is supported in the specified vertical position.
Conditioned sample
The datasheet specifies a sample pH of 4–11 and flow to the internal reservoir.
Process outputs
Two 4–20 mA outputs and Modbus RTU RS485 support plant integration.
Calibration history
The last ten calibration results are retained in the internal datalogger.
Designed for practical sodium monitoring
The 3S-NA separates electronics, standard solutions and the wet section while keeping sodium results and status accessible through the colour touchscreen.
Touchscreen
Review sodium results, status information and analyser functions.
Grab samples
The NA-2 configuration can analyse manually collected external samples unattended.
Automatic calibration
Two-point automatic calibration is available with freely selectable intervals.
Reduced operating costs
Low reagent consumption and a measurement design with no moving parts help reduce routine maintenance.

Sodium analyser technical specifications
Parameter-specific 3S-NA information for specification and application review.
| Measured parameter | Na+ (ppb, ppm, mg/L) |
| Measurement principle | Online potentiometric ion-selective electrode measurement |
| Measuring range | 0.1 ppb to 10 ppm |
| Reproducibility | ±0.2 ppb or ±5%, whichever is greater, at constant temperature |
| Response | Continuous operation; T90 180 seconds from 0 to 10 ppb |
| Sample conditions | 5–45°C; pH 4–11; minimum 3 L/h flow to the internal reservoir |
| Calibration | NA-1 manual one- or two-point; NA-2 automatic two-point with grab sample |
| Power supply | 100–240 VAC, 50/60 Hz; optional 24 VDC |
| Outputs | 2 × 4–20 mA and Modbus RTU RS485 |
| Installation | Vertical wall or rack mounting using fixing hinges |
| Protection and environment | IP54; 10–85% RH non-condensing |
| Dimensions and weight | 905 × 380 × 210 mm; approximately 30 kg |
| Alarms | Three programmable SPDT potential-free relays |
Specifications should be confirmed against the latest 3S-NA sodium datasheet and the agreed application before procurement.
Discuss Your Sodium Measurement
Share the water-system location, expected sodium range, sample temperature and pressure, and required analysis frequency for a 3S-NA application review. Visit PMA, compare the PMA 3S product information, or read how a configurable colorimeter can help reduce operating expenditure.
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